Newtonian gravitation only depends upon radial mass distribution
(e.g., Green's function). It and metric gravitation (mass as a
tensor quantity) are symmetric to parity transformation. (x,y,z)
and (-x,-y,-z) give identical answers. Non-metric gravitation (mass
as a pseudotensor) can be antisymmetric. (x,y,z) and (-x,-y,-z)
give different answers. The proper analysis of spacetime geometry
is test mass geometry (chemically identical, opposite parity mass
distributions). Quantitative geometric parity divergence is ab inito
calculated from atomic coordinates. Dr. Michel Petitjean presents an
extensive
survey of theory in pure and applied mathematics. A novel parity
Eötvös (pronunciation) experiment
is proposed in unmodified apparatus using maximally parity-divergent
-quartz
single crystal test masses. An Equivalence Principle violation
>520 times that allowed for opposed composition test masses is predicted.
Introduction
Table I. Test Mass Property Magnitudes
Table II. Symmetry Groups
Table III. Postulated Gravitation Independence
Table IV. Spin and Parity Operations
Testing the Equivalence Principle
Table V. Equivalence Principle Tests
Table VI. Solar Gravitation At Earth Orbit
Table VII. Horizontal Acceleration vs. Latitude
Symmetry, Chirality, Parity
Figure 1. Chirality compared to Parity
Table VIII. Paired Enantiomorphic Space Groups
Table IX. Comparison Of Gravitation Theories
Optical and Geometric Chiralities
Geometrically Chiral Test Masses
Table X. Candidate Chiral Test Masses
Subtopic Hemiparity Test Masses
Calculated Geometric Chirality/Parity
Table XI. 43 Invalid and 16 Deficient Enantiomorphic Sohncke Space Groups
Table XII. Six Qualified Enantiomorphic Sohncke Space Groups
Table XIII. Benzil Differential Parity Enthalpy of Fusion
Figure 2. Tellurium Atomic Lattice
Figure 3. Tellurium Atomic Lattice with Bonds
Table XIV. Calculated Lattice Parity Divergence, Te and alpha-Quartz
Figure 4. log(1-CHI) vs. log(radius): Tellurium, 505,000 Å Radius
Figure 5. log(1-CHI) vs. log(radius): alpha-Quartz, 1,010,000 Å Radius
Figure 6. log(1-CHI) vs. log(radius): Berlinite, 100,000 Å Radius
Figure 7. log(1-CHI) vs. log(radius): Distorted Te Unit Cells
Table XV. Te Distorted Unit Cells Data
Table XVI. Te Distorted Fractional Coordinates
Table XVII. Te Distorted Fractional Coordinates Data
Table XVIII.Calculated Lattice Parity Divergence, Te Cylinders
Table XIX. Measured Quartz Quality
Green's Function
Table XX. CHI Fluctuations at Small Radius Increments
Table XXI. Quartz CHI at Small Radii
Gravitational Scaling
Table XXII. Compactified Dimensions' Effects
Other Chiral Test Masses
Table XXIII.Mean Atomic Weights
Conclusion
Acknowledgements
References
time, and distance as geometry. General Relativity[5] is a geometric model of gravitation. Einstein's elevator Gedankenexperiment[6] embodies the Weak (Galilean-Newtonian) Equivalence Principle[1]:
mass = (px2 + py2 + pz2 - pt2);
metric signature (+1,+1,+1,-1), Relativity mass = (pt2 - px2 - py2 - pz2);
metric signature (+1,-1,-1,-1), field theory
Inertial reference frames (coordinate systems) have constant relative velocity in a flat spacetime manifold. Accelerating frames with consistent definitions of energy and momentum (or mass and angular momentum) require non-zero spacetime curvature (assuming an asymptotic symmetry group, which obtains: the Bondi-Metzner-Sachs group restricted to the Poincaré subgroup[7]). Local spacetime must have a unique curvature. Local test masses exhibiting non-parallel geodesic trajectories require simultaneous different values of local spacetime curvature. Any paired (sets of) test masses violating the Equivalence Principle empirically falsify metric theories of gravitation at their founding postulate.
- Local bodies fall identically, because
- Gravitational mass (F=mgGM/r2) is indistinguishable from inertial mass (F=mia),
- Regardless of composition,
- Regardless of geometry (internal structure),
- Regardless of mass;
The Weak Equivalence Principle extends to the Strong (Einsteinian) Equivalence Principle :
- Non-rotating free fall is locally indistinguishable from uniform motion absent gravitation. Linear acceleration relative to an inertial frame in Special Relativity is locally identical to being at rest in a gravitational field. A local reference frame always exists in which gravitation vanishes.
- Local Lorentz invariance[8] (absolute velocity does not exist) and position invariance. All local free fall frames are equivalent.
- The Strong Equivalence Principle embraces all laws of nature; all reference frames accelerated or not, in a gravitational field or not, rotating or not, anywhere at any time (frame covariance; global diffeomorphism invariance aside from the Big Bang).
The Equivalence Principle demands that gravitational fields contain a local Minkowski (flat) spacetime reference frame (free fall). Gravitational fields cannot have a stress-energy tensor if free fall exists. If no reference frame makes gravitation locally vanish, spacetime curvature is counter-demonstrated as a violated Equivalence Principle.
General Relativity's physical systems are always spatially separable into independent components. Systems of three or more particles require cluster separability (macroscopic locality). When the system is separated into subsystems, the overall mathematical description must reduce to descriptions of the subsystems. This is vital in scattering problems with two or more fragments.
Quantum mechanics allows entangled states (superpositions of product states) that require a fundamental irresolvable connection within readily demonstrated physical systems (two-slit diffraction, the Einstein-Podolsky-Rosen paradox). Macroscopic locality is violated: Measuring the state of one slit in a double slit experiment alters the observed diffraction pattern to single slit patterns (quantum eraser experiments). Relativistic and quantum views are in conflict. Test masses contrasting an emergent phenomenon that cannot be reduced to a point mass equivalent are novel and important tests.
Weak and Strong Equivalence Principles are coupled[9].
Gravitation studies deny non-point geometric[10]
consequences. Chirality and parity are emergent
phenomena - components collectively evolve discrete symmetry system
properties absent and unpredictable from any smaller subset.
Geometric parity is an obligatory Equivalence Principle challenge
if maximum calculated parity divergence (>99%
divergence for parity pair
-quartz
single crystals) is evaluated as are composition divergences
(0.19% divergence in nuclear binding energy/nucleon
for magnesium vs. beryllium).
| Property | Fraction of Rest Mass |
|---|---|
| rest mass | 100% |
| crystal lattice atomic geometric parity |
99.9775% (*Te) 99.9771% (*HgS) 99.9769% (*PdSbTe) 99.9730% (*AlPO4) 99.9726% (*SiO2) 99.9713% (*benzil) |
| nuclear binding energy (low Z) | 0.76% (2He4) |
| neutron versus proton mass | 0.14% |
| electrostatic nuclear repulsion | 0.06% |
| electron mass | 0.03% |
| unpaired spin mass | 0.005% (55Mn**) |
| nuclear antiparticle exchange | 0.00001% |
| Weak Force interactions | 0.0000001% |
When a set of transformations is closed (any transformation can be expressed as the product of other transformations in the set), the set is called a "symmetry group."
| Group | Transformation | Unmeasurable Quantities |
Conserved Quantities |
|---|---|---|---|
| Rotation, SO(3) | Spatial rotations | Absolute angle | Angular momentum L |
| Translation | Spacetime translations |
Absolute position | Energy E, or Mass M and Momentum P |
| Lorentz | Spacetime rotations and Reflections |
Absolute uniform velocity, Orientation |
Spacetime interval S, Parity P, Time reversal T |
| SL(2,C) (Homogeneous Lorentz) |
Spacetime rotations | Absolute uniform velocity |
S (not P or T) |
| Diffeomorphism (General Coordinate) |
Spacetime curvature (acceleration) |
Absolute acceleration |
Topological invariants* |
| Poincaré | Lorentz plus Translations |
(see above) | L, E (or M) and P |
| U(1) | Scalar Phase Shift | Absolute phase | Electric charge |
| SU(2) | 2-D Phase Shift | Absolute 2-D phase | Isospin |
| SU(3) | 3-D Phase Shift | Absolute 3-D phase | Color |
*Manifolds with multiple differential structures (e.g., 7-D sphere) have multiple, mutually-exclusive equivalence classes of metrics characterized by different, independent definitions of volume (by a factor of the Jacobian under coordinate transformations).
Unitary groups U(1), SU(2) and SU(3) parameter spaces are isomorphic to (in one-to-one correspondence with) the circle, the sphere (a surface) and the "three sphere" (not a ball) respectively. Fields with non-abelian symmetries divide into "electric" (curl-free; e.g., gravitational) and "magnetic" (divergence-free; e.g., inertial) fields as do abelian electromagnetism and the linearized form of Einstein's field equations for weak gravity and slow matter.
| Class | Invariance | Conserved Quantity |
|---|---|---|
| Proper orthochronous Lorentz symmetry |
translation in time (homogeneity) |
energy |
| translation in space (homogeneity) |
linear momentum | |
| rotation in space (isotropy) |
angular momentum | |
| Discrete symmetry |
P, coordinates' inversion | spatial parity |
| C, charge conjugation | charge parity | |
| T, time reversal | time parity | |
| CPT | product of parities | |
| Internal symmetry (independent |
U(1) gauge transformation | electric charge |
| U(1) gauge transformation | lepton generation number | |
| U(1) gauge transformation | hypercharge | |
| U(1)Y gauge transformation | weak hypercharge | |
| U(2) [not U(1)xSU(2)] | electroweak force | |
| SU(2) gauge transformation | isospin | |
| SU(2)L gauge transformation | weak isospin | |
| PxSU(2) | G-parity | |
| SU(3) "winding number" | baryon number | |
| SU(3) gauge transformation | quark color | |
| SU(3) (approximate) | quark flavor | |
| S((U2)xU(3)) [not U(1)xSU(2)xSU(3)] |
Standard Model | |
EP tests exploit external symmetries' observables. Internal symmetries' observables (gauged using fiber bundle theory, e.g., charge conjugation) transform fields amongst themselves leaving physical states (translation, rotation) invariant. A local gauge transformation always exists to make the local gauge-field vanish. Two vector potentials differing only by a gauge transformation give the same field. EP tests opposing properties coupled to internal symmetries are empirical first order default nulls.
Linear and angular momenta, mass-energy, electric charge, and CPT are strongly conserved (black holes). Properties derived from internal symmetries transform fields amongst themselves leaving physical states (translation, rotation) invariant: U(1) symmetry in electromagnetism, U(2) symmetry in electroweak theory, SU(3) in strong force theory. CPT, quark color, baryon number, and lepton generation number are locally conserved. Weak interactions violate parity conservation and violate the remainder. Gravitation has never been challenged with test mass geometric parity.
Parity symmetry obtains when physics is invariant under a discrete
transformation that reverses all space coordinates' signs (x,y,z)
but ignores time (t). Angular momentum and spin (J = r X
p, axial vector or pseudovector), angular velocity, torque,
auxiliary magnetic field (H), magnetic dipole moment, and longitudinal
and transverse polarizations remain constant under parity. Parity
reverses the signs of the position vector (proper or polar vector) of
a particle in space (r to -r), velocity (v = dr/dt),
linear momentum (p), force (f = dp/dt), electric field
(E = -
V),
and electric dipole moment
(
·E).
| JP | Even Parity Object | JP | Odd Parity Object |
|
|---|---|---|---|---|
| 0+ | Scalar (S) | 0- | Pseudoscalar (P) | |
| 1+ | Axial vector (A) | 1- | Polar Vector (V) | |
| 2+ | Tensor (T) | 2- | Pseudotensor | |
Newtonian gravitation requires parity invariant conservative forces. General Relativity models gravitation as a parity invariant rank-2 tensor. Nobody has sought empirical exceptions despite acceptable theoretical loopholes[12] including teleparallel gravitation (below).
External symmetry-derived properties (e.g., parity) act on spacetime.
A Poincaré group gauge theory can be equivalent to the
Einstein-Cartan theory of gravitation[13].
Einstein-Cartan theory operates in Riemann-Cartan spacetime
U4 - a paracompact, Hausdorff, connected,
C
,
and oriented four-dimensional manifold on which are defined a local
Lorentz metric g and a linear affine connection
.
Curvature and torsion tensors can be obtained from
on U4:
Quantum field theories (QFT) with hermitian hamiltonians are invariant under the Poincaré group containing spatial reflections. Parity is a spatial reflection and parity is not a QFT symmetry! QFT are invariant under the identity component of the Poincaré group - the subgroup consisting of elements that can be continuous path joined to the Poincaré group identity; only an orthochronous Poincaré group representation. This subgroup excludes parity and time reversal. All hermitian hamiltonians will contain a symmetry and an observable with the properties of parity, even though the Hamiltonian will not be symmetric under space reflection. QFT with non-hermitian Hamiltonians can have real and positive energy spectra with PT invariance, but do not contain parity invariance alone[14]. Metric and quantum field theories of gravitation are tested by the parity Eötvös experiment.
Supersymmetric (SUSY, gauge symmetry plus spacetime symmetry) grand unified theories relating fermions and bosons to each other contain added allowances for symmetry breaking (inserted soft breaking terms into the Lagrangian where they maintain the cancellation of quadratic divergences)[15]. When global symmetry contracts to local symmetry, supergravity (SUGRA) emerges: if one gauges the SUSY transform, because of the SUSY algebra, one inevitably gets a gravitation theory)[16]. Supergravity by itself is not a renormalizable quantum theory.
A gravitational stress-energy (energy-momentum) pseudotensor constructs volume integrals for total gravitational four-momentum and total angular momentum. Teleparallel gravitation can allow a gravitational stress-energy pseudotensor obtained by comparing vectors at different points of spacetime - a coframe field - unlike ordinary General Relativity. (Teleparallel theories wholly equivalent to General Relativity are inoperative here.) When the coframe field changes, the pseudotensor changes (not gauge-invariant; not covariant under general coordinate transformations)[17]. This defines an integral energy-momentum obeying an exact conservation law. It is an observable, and it can be sensitive to parity inversion[18] - "a redistribution of energy between material and gravitational (coframe) fields is possible in principle."
(The difference between the Weitzenböck and Levi-Civita connections is "contorsion" quantifying coframe field twist as measured by the Levi-Civita connection. Contorsion can be expressed as the torsion of the Weitzenböck connection. The Levi-Civita connection can be expressed as the Weitzenböck connection and its torsion. The Ricci scalar curvature can be expressed as the Weitzenböck connection and its torsion. The Lagrangian for General Relativity therefore can be expressed purely in terms of the coframe field - in a way that is not symmetric to parity transformation.)
Physics seeks Equivalence Principle empirical violation. Tests often examine quantities evolved from internal symmetries via Noether's theorem. Internal symmetries by definition - a local gauge transformation always exists to make the local gauge-field vanish - do not affect spacetime. Studies contrasting baryon number, isospin, hypercharge, lepton vs. baryon number... are automatic null results.
Geometric parity is the only untested physical property arising from an external symmetry. Parity is an absolutely discrete symmetry that cannot be approximated by a Taylor series or a sum of infinitesimals. Noether's theorem with its dependence upon smooth Lie groups is inappropriate.
The existence of a symmetry operator implies the existence of a conserved observable. Given G is the Hermitian generator of nontrivial unitary operator U (e.g., parity), then if U commutes with Hamiltonian H so does G [H,G]=0. If U commutes with H it is a symmetry and a conserved quantity. Any system that is initially in an eigenstate of U evolves over time to other eigenstates having the same eigenvalue.
U= c
then,
Uexp(-itH)= exp(-itH) U
[U commutes with H]
= exp(-itH) c
= c exp(-itH)![]()
so exp(-itH)
is again an eigenstate of U, with the same eigenvalue c.
Discrete symmetries also give conserved quantities in classical
mechanics (e.g., bifurcation theory of dynamical systems). Parity
the symmetry is coupled to geometric parity the property.
| Year | Investigator | Accuracy | Method |
|---|---|---|---|
| 500? | Philoponus[20] | "small" | Drop Tower |
| 1585 | Stevin[19] | 5·10-2 | Drop Tower |
| 1590? | Galileo[2] | 2·10-2 | Pendulum, Drop Tower |
| 1686 | Newton[3] | 10-3 | Pendulum |
| 1832 | Bessel[21] | 2·10-5 | Pendulum |
| 1910 | Southerns[22] | 5·10-6 | Pendulum |
| 1918 | Zeeman[23] | 3·10-8 | Torsion Balance |
| 1922 | Eötvös[24] | 5·10-9 | Torsion Balance |
| 1923 | Potter[25] | 3·10-6 | Pendulum |
| 1935 | Renner[26] | 2·10-9 | Torsion Balance |
| 1964 | Dicke,Roll,Krotkov[27] | 3·10-11 | Torsion Balance |
| 1972 | Braginsky,Panov[28] | 10-12 | Torsion Balance |
| 1976 | Shapiro, et al.[29] | 10-12 | Lunar Laser Ranging |
| 1981 | Keiser,Faller[30] | 4·10-11 | Fluid Support |
| 1987 | Niebauer, et al.[31] | 10-10 | Drop Tower |
| 1989 | Heckel, et al.[32] | 10-11 | Torsion Balance |
| 1990 | Adelberger, et al.[33] | 10-12 | Torsion Balance |
| 1999 | Baeßler, et al.[34] | 5·10-13 | Torsion Balance |
| 2010? | MiniSTEP[35] | 10-17 | Earth Orbit |
Contrasting compositions classically define[36] "different" test masses : baryon number (N+Z), isopin (N-Z)/2, Yukawa forces[37]; gravitational self-energy[38]; electron spin (Dy6Fe23 and HoFe3[39]; 94% of Alnico 5 magnetic field) versus electron orbital angular momentum (37% of Sm2Co17 magnetic field) - a mole of electrons masses an insignificant 5.4858·10-4 grams; neutrino-antineutrino exchange in different nuclei[40]; and inverse square deviations at small radii (string then M-theory[41]). 400+ years of exquisite tests, notably those derived from Vásárosnaményi Báró Eötvös Loránd[24], null to differential detection limits.
Ferrimagnet Dy6Fe23 has no external magnetic field at -1°C. It has 0.4 unpaired electrons/formula unit, or 97 nanograms of net unpaired spins/g test mass. It is ridiculously dilute. This spin test mass is calculated to display measurable spacetime torsion interaction as a cylinder 20 meters (!!!) in diameter and length weighing some 50,000 metric tonnes (25% more than the largest WWII Essex-class aircraft carrier fully loaded and fueled).
Quantifiable composition divergences arise in quantum mechanics, quantum chromodynamics, and relativistic electronic effects (gold[42]). To the extent that bodies are identical they are equivalent. Mirror-image chiral and parity pair bodies cannot be identical by definition. 65 Sohncke space groups of 230 total[43] describe chiral crystal configurations. 22 Sohncke space groups are eleven enantiomorphic parity pairs. Metric theories of gravitation are falsified at the postulate level if extreme mirror-image chiral or parity pair bodies are not Eötvös experiment nulls.
Starting in 1889 Eötvös' torsion balance tested the Equivalence
Principle. Masses gravitate toward Earth's center. Given two (sets of)
test masses, one at each end of a fiber-suspended rotor, the horizontal
component of centripetal force is directed away from the Earth's spin
axis proportional to inertial mass. Net torque twists the fiber if
mGM/r2
ma. An attached mirror reflects light, amplifying angular deviation
into an interferometer. Dicke[27] used
Earth's free fall in the sun's gravitational field[44],
| Acceleration, cm/sec2 | Orbital Position | Date |
|---|---|---|
| 0.593008 | One astronomical unit | |
| 0.613307 | Geocenter perihelion |
2001-2101 mean value |
| 0.613393 | 2020, 05 January | |
| 0.613214 | 2098, 05 January | |
| 0.613305 | Earth/Moon barycenter perihelion |
2001-2101 mean value |
| 0.613381 | 2020, 04 January | |
| 0.613252 | 2098, 04 January | |
| 0.573700 | Geocenter aphelion |
2001-2101 mean value |
| 0.573786 | 2085, 04 July | |
| 0.573626 | 2019, 04 July | |
| 0.573702 | Earth/Moon barycenter aphelion |
2001-2101 mean value |
| 0.573764 | 2097, 05 July | |
| 0.573654 | 2019, 05 July | |
and surface inertial centripetal acceleration (sidereal day, WGS 84;
sea level unless noted) of Earth's rotation.
r = (6378136.46)[1-([sin2(lat)]/298.257223563)] meters
a = (3.380199)(cosine[lat])/[1-(0.006694380)cosine2(lat)] cm/sec2
horizontal component of a = a[sin(lat)]
| Resultant, cm/sec2 | Geocentric Latitude, degrees | Horizontal Component, sin(lat) |
Centripetal Acceleration, cm/sec2 |
|
|---|---|---|---|---|
| 3.66 | 45 | 550 mph east ground speed |
commercial airliner |
|
| 9.51 | 45 | 1336 mph east ground speed |
Concorde | |
| 1.46490 | 60 | 0.866025 | 1.691516 | |
| 1.58993 | 55 | 0.819152 | 1.940941 | |
| 1.66673 | 50 | 0.766044 | 2.175761 | |
| 1.69294 | 45 | 0.70711 | 2.394172 | |
| 1.69294 | 44.951894 | 0.706513 | 2.396188 | |
| 1.66770 | 40 | 0.642788 | 2.594484 | |
| 1.59175 | 35 | 0.573576 | 2.775137 | |
| 1.46736 | 30 | 0.500000 | 2.934715 | |
| 1.29826 | 25 | 0.422618 | 3.071958 | |
| 1.08960 | 20 | 0.342020 | 3.185778 | |
| 0.84770 | 15 | 0.258819 | 3.275266 | |
| 0.57993 | 10 | 0.173648 | 3.339705 | |
| 0.29446 | 5 | 0.087156 | 3.378578 | |
| 0 | 0 | 0 | 3.391570 | |
g = (978.032677)[1+(0.00193185139)sin2(lat)]/Any torque is diurnally modulated: For an Eötvös torsion balance with masses aligned east-west, maximum torque occurs at local noon or midnight when Earth's orbit is maximally anti-parallel or parallel to its rotation. Six hours offset torque is minimized. For test masses aligned north-south, torque maxima occur at 0600 hrs and 1800 hrs. The entire apparatus may be rotated with phase-lock detection to decouple noise.[1-(0.00669437999)sin2(lat)] cm/sec2
dg/dh = 0.000308766[1-(0.0014665)sin2(lat)] cm/sec2-meter
dg/ds = -0.0008109[cos[(2)(lat)]+(0.0022)cos[(4)(lat)]-(0.0033)cos[2(lat)]sin2(lat)] cm/sec2-kmr = geocentric radius
a = total centripetal acceleration
lat = latitude
g = gravitational acceleration
h = altitude above sea level
s = distance
Gravitational versus inertial mass anomaly is the dimensionless
Eötvös parameter
, the
difference divided by the average of mg/mi
for the two sets of test masses "A" and "B."
= 2[(mg/mi)A - (mg/mi)B] / [(mg/mi)A + (mg/mi)B]
Falling mass gravimeters detect 10-9 of ambient
gravity[45]. Levitated dual sphere
superconducting gravimeters[46] sense
10-11. Eötvös balances discern
~ 10-13 where room temperature vibration of component atoms
interferes[47] as noise. Cryogenic
2.2°K Eötvös apparatus is being
debugged[48]. Drag-shielded free-fall
apparatus with
~ 10-15 is proposed[49].
Cn proper rotation
axes (360°/n) do not affect chirality. Sn improper
(rotation-reflection, alternating) axes are Cn
rotations followed by reflection through a plane normal to
the Cn axis
(Eleven parity pairs of enantiomorphic space groups[43] have inverse lattices in which all three spatial coordinates reverse in sign. Unlike chirality, parity changes the space group:
| P31 | P3112 | P3121 | P41 | P4122 | P41212 | P4132 | P61 | P62 | P6122 | P6222 | ||
| P32 | P3212 | P3221 | P43 | P4322 | P43212 | P4332 | P65 | P64 | P6522 | P6422 |
Enantiomers are not interconverted by time reversal plus proper spatial rotation in "true chirality"[50]. Quantitative geometric parity can be calculated[51]. Macroscopic chirality is a complex[52] concept. Liaisons between paired chiral bodies (a left shoe on a left or right foot) exhibit different free energies. Parity Eötvös experiments are profound tests of spacetime geometry.
Spacetime events are empirically left-handed: cobalt-60 beta-decay parity violation[53]; K-meson[54] and B-meson[55] decay charge-parity violation. Parity violation[56] is inarguable. Enantiomeric excited nuclei have different energy levels for otherwise identical transitions[57]. All atoms are intrinsically homochiral[58]. Excess matter vs. antimatter requires chiral discrimination[59]. A weakly interacting reverse-parity entire universe is proposed[60]. Linearly polarized massless photons traversing intergalactic space do not show optical rotation[61]. A photon is not a valid inertial reference frame. Massed interactions are different.
Gravitation arises from spacetime curvature (Riemann, metric), torsion (Weitzenböck, affine[13]), or both. Teleparallelism has torsion acting as a force, analogous to electrodynamics' Lorentz force equation, without geodesics. Parity pair Eötvös experiments offer self-similar helical geometry in greater active masses, subtended areas, and volumes than spin-polarized test masses[39,62] whose Eötvös experiments null within experimental error. Non-metric gravitation theories also postulate the Equivalence Principle[63].
Metric theories of gravitation postulate[64] spacetime is a Lorentzian manifold, test particles pursue space-time geodesics (all sufficiently small bodies subject only to gravitational interactions and starting with the same initial positions and velocities follow identical spacetime trajectories), and the Strong Equivalence Principle obtains. Component form physical laws move from flat into curved spacetime by replacement of partial derivatives with covariant derivatives (note factor ordering given non-commutation of covariant derivatives, as classical mechanics transforms into quantum mechanics). Geometry's response to matter distribution, Einstein's field equations, arises from the principle of least action. Equivalence Principle violation annuls spacetime curvature.
Local symmetries create conservation laws through Noether's theorem[65]. A conserved quantity derives from each symmetry commuting with time, and the reverse. A divergence-free current (conserved property) arises if the Lagrangian or the action is invariant under continuous transformation.
A symmetry can be broken explicitly - a term in the action or equations of motion may not be invariant. A symmetry can be broken anomalously - not all classical theory symmetries exist in the corresponding quantum theory. Quantum field theory anomaly spoils renormalizability. Anomaly absence in the Standard Model is crucial. A symmetry can be broken spontaneously if it is an exact symmetry of the equations of motion but not of a particular solution therein. Noether's theorem holds if the symmetry is not broken explicitly. Conservations can be relaxed in subsystems displaying reduced symmetry (Born scattering approximation, Fermi's golden rule, Snell's law).
A classical field theory conserved quantity does not demand a quantum field theory conserved quantity in kind. Parity Eötvös experiments offer measurable anomalies between General Relativity's continuous symmetries and test masses' discrete symmetries.
| Theory | Metric | Other Fields |
Free Elements | Status |
|---|---|---|---|---|
| Newton (1687) [67] |
Nonmetric | Potential | None | Nonrelativistic theory |
| Nordstrom (1913) [66,68] |
Minkowski | Scalar | None | Unpredicted light detection |
| Einstein (1915) [67,68] |
Dynamic | None | None | Viable |
| Whitehead (1922) [69] |
Fixed | Tensor | 1 parameter [70] |
Possibly viable[71] |
| Belifante-Swihart (1957) [68] |
Nonmetric | Tensor | K parameter | Contradicted by Eötvös experiments |
| Brans-Dicke (1961) [67,68,72] |
Generic Scalar |
Dynamic Scalar |
Viable for |
|
| Tensor (1970) [80] |
Dynamic | Scalar | 2 free functions |
Viable |
| Ni (1970) [67,67] |
Minkowski | Tensor Vector Scalar |
1 parameter 3 functions |
Preferred-frame effects unobserved |
| Will-Nordtvedt (1972) [68] |
Dynamic | Vector | None | Viable |
| Rosen 1973) [68] |
Fixed | Tensor | None | Contradicted by binary pulsar data |
| Rastall (1976) [68] |
Minkowski | Tensor Vector |
None | Viable |
| Variable Mass,VMT (1977) [68] |
Dynamic | Scalar | 2 parameters | Viable for wide range of parameters |
| Modified Newtonian Dynamics, MOND (1983) [73] |
Nonmetric | Potential | Free Function | Nonrelativistic theory |
Gravitation is modeled by loop quantum theory[74], brane/string/M-theory[75], Lorentzian lattice quantum gravity[76]..., though few predictions exist to be tested. M-theory fails to predict the absence of supersymmetry at low energies, the presence of a positive cosmological constant, and the utter absence of a massless scalar field that its component string theories predict in abundance. Loop quantum theory predicts unobserved vacuum dichroism - lightspeed being very slightly smaller for high energy photons.
The Michelson-Morley experiment showed space is isotropic for massless photons to differential 10-8 in 1887 and 1.7·10-15 in 2002[77]. The Higgs field[78] uncouples massless and massed particles. Single crystal silicon polarized interferometry (revolving Earth orbiting the sun) detects 10-2[79] to 10-3[80] relative, ten orders of magnitude too insensitive (Colella-Overhauser-Werner[81] and Bonse-Wroblewski[82] neutron interferometers; Kasevich-Chu[83] atom interferometers).
Gyrotropy is assigned spiraling toward the observer, geometry spirals away from the observer. Dextrorotatory gyrotropy is levorotatory structure (optically right-handed quartz is space group P3221). Distant from optical transitions in ionic crystals[86]:
- Smaller pitch (repeat distance) of atomic helices gives larger gyrotropy.
- Smaller radial distance from helical axes gives larger gyrotropy.
(Smaller relative radius or pitch increases geometric parity. Smaller radius and pitch together leave scale invariant geometric parity unaltered)- Larger electronic (Pauling) polarizability gives larger gyrotropy.
- Tangential or radial (reverses the contribution) polarizability orientation in the plane normal to the helical axis dramatically alters gyrotropy.
Solid state optical activity theory[87] flags three irreducible tensor components, the last two of which tolerate mirror planes of symmetry (gyrotropy without chirality):
- Pseudoscalar, from molecular chirality and persists in disordered solution.
- Vector. A property of pyroelectric lattices.
- Pseudodeviator, from lattice symmetry. Silver thiogallate[88], AgGaS2 with non-polar achiral tetragonal space group I-42d (#122), has immense optical rotatory power: 522°/millimeter along [100] at 497.4 nm, reversed along [010].
Gyrotropy arises from differing refractive indices (n) for left- and right-circularly polarized light in a medium. Gyrotropy summed over the electromagnetic spectrum vanishes:
Chiroptical methods do not measure geometric parity.
- Oscillator strength or f-sum rule[89]. The f-values sum to unity for all transitions from a given state;
- The Thomas-Reiche-Kuhn sum rule[90]. The photoabsorption cross section integral equals the total number of electrons involved in the collective excitation.
- Kramers-Kronig relationship[91]. Refractive index has a real part (n) arising from phase velocity and an imaginary part (k) arising from absorption. Optical rotatory dispersion is the real part and circular dichroism is the imaginary part of one complex spectrum.
- The sum over (n-1) across the electromagnetic spectrum is zero. The difference between two (n) for orthogonal polarizations sums to zero overall[92].
| Chiral Test Mass | Temp, °K | a-axis, Å |
b-axis, Å | c-axis, Å | Volume,
Å3 | Density, gm/cm3 |
Space Group |
|---|---|---|---|---|---|---|---|
| grey Selenium[94] | 300 85 2* |
4.3712 4.304 4.278 |
4.3712 4.304 4.278 |
4.9539 4.968 4.974 |
81.975 79.650 78.909 |
4.798 4.935 4.985 |
P3121 P3221 |
| Tellurium[95] | 4.456 | 4.456 | 5.921 | 101.82 | 6.243 | P3121 P3221 |
|
| neutron diffraction x-ray diffraction |
278 298 13 |
4.9134 4.9137 4.9021 |
4.9134 4.9137 4.9021 |
5.4052 5.4047 5.3977 |
113.01 113.01 112.33 |
2.649 2.649 2.665 |
P3121 P3221 |
| 4.145 | 4.145 | 9.496 | 141.29 | 8.203 | P3121 P3221 |
||
| Berlinite, AlPO4 | 4.766 4.9438 |
4.766 4.9438 |
10.724 10.9498 |
210.96 231.771 |
2.880 2.621 |
P3121 P3221 |
|
| Palladium antimonide telluride, PdSbTe[93] |
6.5362 | 6.5362 | 6.5362 | 279.24 | 8.463 | P213 | |
| Azatwistanone[97] (model) | 6.662 | 13.36 | 8.606 | (756.60) | 1.327 | (P21/n) | |
| [4]Triangulane[98] | 120 | 5.798 | 10.434 | 11.872 | (718.21) | 1.112 | P212121 |
| [5]Triangulane[99] | 110 | 12.024 | 5.3156 | 7.609 | 443.17 | 1.096 | C2 |
| benzil | 294 100 70 |
8.402 8.356 14.380 |
8.402 8.356 8.373 |
13.655 13.375 13.359 |
834.81 808.76 1608.1 |
1.255 1.295 1.303 |
P3121 P3221; P21 |
Chiral crystals are complex objects[86]: Quartz (SiO2; no detectable gyrotropy 56.16° from crystallographic [0001]), paratellurite (TeO2; P41212, P43212), (HgS; P3121, P321), langasite[100] (La3Ga5SiO14; P321), berlinite (AlPO4; P3121, P3221), Bi12(Si, Ge, or Ti)O20 (I23), sodium bromate and chlorate (P213) all possess at least one traceable counter-helix to the dominant atomic helices. Space group P213 in QCM often shows good CHI growth, COR=1 and DSI=0 through 1100 atoms contained. Ferroelectric crystals are polarity twinned. Grey selenium must be grown from hot aniline solution[101] or different allotropes obtain; melt growth is disordered. Mechanical trauma deeply disrupts its lattice.
Achiral benzil[102] crystallizes in enantiomorphic space groups. A twinning phase transition[103] occurs at 84°K. Boules obtain by Bridgman-Stockbarger directional solidification[104]. Good crystals require solution growth as hot solid plastically deforms into lattice dislocations. Molecular solids have undesirable large unit cells.
An Eötvös rotor must be balanced around its vertical supending
fiber for mass and moments of inertial overall. Petitjean's mathematics
demands each test mass have three equal moments of inertia for maximum
parity divergence. Full parity Eötvös experiment test masses
are then explicit - identical chemical compositions, macroscopically
identical forms, single crystal solid convex bodies without surface
drilling or internal hollowing, and extremal opposite parity crystal
lattices. Solid spheres or solid right cylinders with height equal to
(radius)
3 qualify.
Quartz offers a unique opportunity to perform two hemiparity Eötvös experiments, space group P3121 or P3221 quartz against amorphous fused silica. Different densities must be compensated. As all test masses are gold plated, this is straightforward.
dquartz = 2.649 g/cm3
dsilica = 2.203 g/cm3
dgold = 19.3 g/cm3
A quartz ball of radius R would be balanced by a fused silica ball of radius (R-r) with a vacuum-plated gold shell of thickness r. The general solution, sphere or cylinder, is
r3 - 3Rr2 + 3R2r - [(dquartz-dsilica)/(dgold-dsilica)]R3 = 0
r3 - 3Rr2 + 3R2r - (0.0260864)R3 = 0
www.1728.com/cubic.htm
For R = 1 centimeter in quartz, r = 87.72 micrometers in gold.
Eötvös balances typically employ test mass right cylinders or spheres. A homogeneous isotropic solid sphere is the most symmetric figure in three dimensions. It possesses the following symmetry elements:
The rigorous abstract mathematics of chirality has been extensively examined and reduced to QCM software. CHI[51] is the quantitative calculation of the geometric parity divergence of N points. CHI is globally minimum for all rotations (R) and translations (t) for all correspondences (P) permitted by the colors and/or graph:
CHI = (d)[Min{P,R,t}D2]/4Twhere d is the Euclidean dimension, D2 is the sum of the N squared-distances between the set and its parity inversion for a fixed pairwise correspondence with coincident centers of mass, and T is the geometric inertia of the set. All points are assigned equal mass, though their labels may differ. CHI varies between zero (exactly superposable (x,y,z)-parity inversions) and one (perfect divergence) inclusive. CHI is a continuous function of nuclear coordinates only - independent of translation, scale, and size. One value exists for a given target and its inverse lattice. It detects zero and approach toward zero. It does not require empirical constraints.
CHI is limited by three conditions:
Parity is a subset of chirality. Lattice chirality is an emergent phenomenon wherein components collectively evolve discrete symmetry system properties absent and unpredicted from any smaller subset. Lattice chirality does not simplify below a microscopic packing unit seamlessly translated along its axes in three dimensions into a self-similar macroscopic crystal. Four possibilities obtain:
(2) includes local achiral superunits as in La Coupe du Roi[105]. Cut a ball (apple) in from a pole to its equator along a great circle (lines of longitude 180° apart) with a plane. Repeat rotated 90° at the other pole (perpendicular planes). Make two equatorial cuts in the same direction, surface to center radial sectors, from the equatorial edge of one pole cut to the other and again on the opposite side (rotate about the polar axis; cut, skip, cut). The ball (apple) cleaves into identical homochiral halves. Homochiral components can assemble into a zero chirality lattice. Aspects of (2) lessen parity pair divergence.
Aspects of (2) weaken parity Eötvös experiments. If the set of points corresponding to positions occupied by all symmetry copies of the asymmetric unit is intrinsically chiral (3132 4143 6165 6264 screw axes), CHI>zero even if the formula units are achiral. 21 42 63 or no screw axes can allow geometric chirality to decrease with volume even if formula units are intensely chiral. 10 Sohncke space groups become achiral if their unit cell contents are achiral. 6 Sohncke space groups have no screw axes at all. 21 additional Sohncke space groups contain both left and right screw axes. 22 additional Sohncke space groups contain 21 42 63 that are each simultaneously left- and right-handed screws with the same screw vector[106]. These 59 space groups contain conflicting geometries that decrease CHI increase with increasing lattice sample radius.
| Deficiencies | Space Groups | |||||
|---|---|---|---|---|---|---|
| Zero intrinsic lattice chirality |
P1 | P2 | P21 | C2 | P4 | P42 |
| I4 | P3 | P6 | P63 | |||
| 21 42 63 screw axes only |
P2221 | P21212 | P212121 | C2221 | C222 | F222 |
| I222 | I212121 | P4222 | P42212 | I422 | P6322 | |
| Cn axes only | P222 | P422 | P4212 | P312 | P321 | P622 |
| Opposite sense helices |
I41 | I4122 | R3 | R32 | P23 | F23 |
| I213 | P432 | P4232 | F432 | I23 | P213 | |
| P4132 | F4132 | I432 | P62 P64 |
P6222 P6422 |
I4132 P4332 |
|
| Same-sense helices plus 21 | P41 P43 |
P4122 P4322 |
P41212 P43212 |
P61 P65 |
P6122 P6522 |
|
The three pairs of remaining enantiomorphic space groups possess unique screw axes[106]. These structures exclude primary conflicting symmetries and support maximal CHI increase with increasing lattice sample radius . A given material's lattice must still be examined with QCM for graph theoretic correspondences beyond the identity correspondence.
| Acceptable | Space Groups | ||
|---|---|---|---|
| Same-sense helices |
P31 P32 |
P3112 P3212 |
P3121 P3221 |
10-13 mass anomaly is 2.148 cal/gram. Water hydrogen bond energy[107] is 5.57 kcal/mole (328 cal/gram), carbon-carbon single bond energy is 85 kcal/mole (3500 cal/gram). Test the Equivalence Principle with calorimetry [108]. Parity pair single crystals' heats of combustion vary with geographic orientation, local time of day, and impressed inertial acceleration.
| Property[109] | Value | ||
|---|---|---|---|
| Molecular weight |
210.2322 g/mol | ||
| Triple point |
94.864°C | ||
| Dynamic melting point |
Onset 94.43°C |
Meniscus 94.77°C |
Melt 95.08°C |
| Thermodynamic melting point |
Onset 94.55°C |
Meniscus 94.72°C |
Melt 94.86°C |
| Enthalpy of fusion mp = 94.82°C |
112.0 J/g 26.77 cal/g |
23.546 kJ/mol 5.6276 kcal/mol |
|
| Enthalpy of fusion mp = 94.85°C |
110.6 J/g 26.44 cal/g |
23.26 kJ/mol 5.559 kcal/mol |
|
| Enthalpy of fusion mp = 94.86°C |
112.0 J/g 26.76 cal/g |
23.54 kJ/mol 5.626 kcal/mol |
|
| Enthalpy of parity divergence |
26.96 J/g 6.444 cal/g |
5.668 kJ/mol 1.355 kcal/mol |
|
| Differential enthalpy of parity divergence |
~24% for 3·10-13 g/g parity anomaly E = (3·10-16 kg)(299,792,458 m/sec)2 |
||
Putting unique atoms' fractional coordinates through space group symmetry operations[43] populates the unit cell, the smallest repeated lattice volume. Selenium and tellurium unit cells contain three atoms, but three points define an achiral plane. Moved, the unit cells each contain six half-atoms - the repeating chiral unit as an emergent phenomenon. Selenium and tellurium values would not change given CHI weighted for atomic mass and fractional unit cell occupancy. The goal is the fastest growing lattice CHI from the smallest unit cell with the smallest volume/atom and heaviest atoms in the best parity space group.
The abstract mathematics of quantitative parity divergence only sees points' coordinates for analysis. A 3300 Å3 cube of tellurium lattice with 98 atoms (innermost 20% electron probability ellipsoids shown) appears to be a spatially repeating collection of points. Where is the parity divergence or even chirality?
Drawing nearest neighbor distances reveals aligned homochiral 3-fold helices. Perception and "common sense" are irrelevant. Rigorous mathematics is the only valid analysis. (Look beyond the screen to relax your eyes' convergence. The two-block image will double, one view from each eye. Increasing distance from the screen eases the deconvergence process. As you go increasingly walleyed the images will move further apart causing the center blocks to overlap. When the bottom crosses merge you can look into the 3-D image.)
A macroscopic test mass is an apparently continuous medium. Lattice volumes are quantized by nearest neighbor distances at scale. The number of calculations needed to determine CHI grows as the products of factorials of the number of each color of atom (not each chemical element) given full QCM diagnostics. A lattice is qualified by QCM evaluation of consecutive angstrom increment radii from half the longest unit cell axis length to at least 1000 atoms contained. A QCM 1000-atom run will typically require 10-20 CPU-hours in an RS6000/Power3 given connectivity-optimized HyperChem *.hin file input. It is a quirk of QCM graph theory analysis that 15 points input as *.xyz file format would require more than the age of the universe to calculate - to give the same answer as *.hin format input after a few minutes.
QCM begins with enumeration of graph automorphisms in concentric layers of the array starting at its origin. "Direct symmetry index" DSI, the normalized minimized sum of the N squared-distances between the vertices of the d-set and the permuted d-set, measures the set's similarity to itself. A set having no direct symmetry in a d-dimensional Euclidean space is still not symmetric after immersion in a higher dimensional space while a nonspecific chiral set would become achiral. DSI>0 beyond a few contained unit cells is a disqualification for extremal parity-divergent test masses.
"Correspondences" COR includes the identity element but is not a count of group theory symmetry elements. COR>1 beyond a few contained unit cells is a disqualification for extremal parity-divergent test masses. Assigning different atom labels (SiO2) does not default assign different graph theory point colors. QCM numeric outputs are independent of input file structure format, atom connectivity (if any), and list ordering. All points are assigned unit weight. Mass is mass.
If DSI=0 and COR=1, a FastCHI subset of QCM is valid. FastCHI coding calculates CHI (how a set is not similar to its parity inversion) linearly with the number of atoms (runs in O(n) time and O(1) space). A 2 GHz Linux PC in AMD Athlon hardware (Wintel is 40% slower) can examine ~109 atoms/second. Large quartz radii were run in a cluster of 16 AMD Opteron-848s in 30 days. Tellurium, quartz, and berlinite were given 609, 90,386 (150,000 CPU-hrs; 444 quadrillion atoms), and 571 radius samplings respectively to calculate the following:
| Sphere Radius, Å | Lattice CHI | Total Atoms |
Unit Cells | Volume, Å3 |
|---|---|---|---|---|
| Unit Cell* Tellurium Quartz Berlinite |
0.018926 0.173940 0.174566 |
6 11 23 |
1 1 1 |
102 113 211 |
| Quartz 3.6 Berlinite 5.0 |
0.843228753630922340 0.928954111975661469 |
14 46 |
1.6 2.6 |
176 539 |
| 10 | 0.953161251843284545 0.989463287292071760 0.922918192326544688 |
126 340 350 |
42 38 19 |
4,189 4,269 4,102 |
| 20 | 0.994970730830562692 0.991987685060543311 0.989437910906527996 |
987 2,670 2,854 |
329 297 159 |
33,510 33,528 33,449 |
| 30 | 0.995341618942362163 0.994391347133448844 0.999136218439710468 |
3,315 9,014 9,658 |
1,105 1002 537 |
113,100 113,200 113,200 |
| 40 | 0.994311225094353860 0.995770871078683400 0.999632392784788830 |
7,906 21,346 22,888 |
2,635 2,372 1,272 |
268,100 268,000 268,200 |
| 50 | 0.997182871713665811 0.997497356338878373 0.997751761704918893 |
15,428 41,696 44,665 |
5,143 4,633 2,481 |
523,600 523,600 523,500 |
| 100 | 0.998674087455959555 0.999455952622276367 0.999643499178059791 |
123,411 333,526 357,384 |
4.11·104 3.71·104 1.99·104 |
4.19·106 4.19·106 4.19·106 |
| 500 | 0.999991634437844450 0.999980456860055180 0.999989604104047446 |
15,427,878 41,696,416 44,676,376 |
5.14·106 4.63·106 2.48·106 |
5.24·108 5.24·108 5.24·108 |
| 1,000 | 0.999993481890267883 0.999997440127579185 0.999998427421108820 |
123,422,301 333,575,254 357,408,684 |
4.11·107 3.71·107 1.98·107 |
4.19·109 4.19·109 4.19·109 |
| 2,000 | 0.999998519283409702 0.999999080483513838 0.999999455994921283 |
987,378,232 2,668,598,322 2,859,270,260 |
3.29·108 2.97·108 1.58·108 |
3.35·1010 3.35·1010 3.35·1010 |
| 5,000 | 0.999999871340933588 0.999999789636193490 0.999999929783070689 |
15,427,793,636 41,696,845,260 44,676,133,458 |
5.14·109 4.63·109 2.48·109 |
5.24·1011 5.24·1011 5.24·1011 |
| 10,000 | 0.999999897747013216 0.999999968983088517 0.999999980194705342 |
123,422,354,560 333,574,731,752 357,409,097,084 |
4.11·1010 3.71·1010 1.99·1010 |
4.19·1012 4.19·1012 4.19·1012 |
| 20,000 | 0.999999983730030373 0.999999992565814146 0.999999990115051648 |
987,378,792,095 2,668,597,813,994 2,859,272,764,336 |
3.29·1011 2.97·1011 1.59·1011 |
3.35·1013 3.35·1013 3.35·1013 |
| 100,000 | 0.999999999546726956 0.999999999648281730 0.999999999778529238 |
123,422,348,782,767 333,574,726,196,900 357,409,096,311,540 |
4.11·1013 3.71·1013 1.98·1013 |
4.19·1015 4.19·1015 4.19·1015 |
| Tellurium 200,000 300,000 400,000 505,000 |
0.999999999810150121 0.999999999962125567 0.999999999948796222 0.999999999981536820 |
987,378,790,078,890 3,332,403,416,661,100 7,899,030,320,918,100 15,895,271,169,403,000 |
3.29·1014 1.11·1015 2.63·1015 5.30·1015 |
3.35·1016 1.13·1017 2.68·1017 5.39·1017 |
| Quartz 200,000 300,000 400,000 500,000 750,000 1,010,000 |
0.999999999899102952 0.999999999990628857 0.999999999964449503 0.999999999987239756 0.999999999987958381 0.999999999994484622 |
2,668,597,809,177,800 9,006,517,605,688,300 21,349,690,977,976,000 41,698,615,192,377,000 140,732,826,273,680,000 343,696,999,447,690,000 |
2.97·1014 1.00·1015 2.37·1015 4.63·1015 1.56·1016 3.82·1016 |
3.35·1016 1.13·1017 2.68·1017 5.24·1017 1.77·1018 4.32·1018 |



The berlinite unit cell is the
-quartz
structure with a doubled c-axis, Si-O- vs. Al-O-P-0-. If atoms are taken to be anonymous
mass the c-axis doubling vanishes. The smaller the volume/atom the faster CHI
vs. radius asymptotically approaches CHI=1, and the less positive is the graph
intercept of log(1-CHI) vs. log(radius).
| Lattice | Volume, Å3/atom |
Intercept |
|---|---|---|
| Tellurium | 33.939 | 0.788633 |
| Quartz | 12.557 | 0.546185 |
| Berlinite | 11.720 | 0.506840 |
Te unit cell axes are a,b=4.456 Å, c=5.921 Å. The a,b-axes or c-axis were given large arbitrary variations and CHI was progressively calculated from 5.1-13 Å radius up to a 10,000 Å radius ball with 390-430 radius samplings for the test cases. (The mathematics of CHI is sensitive to shape but not to scale.)

Table XV. Te DISTORTED UNIT CELLS DATA
| Lattice | a,b-axes, Å | c-axis, Å |
Unit Cell Volume, Å3 | Slope | Intercept | Total Atoms |
|---|---|---|---|---|---|---|
| Theory, Te | -2 | arbitrary | ||||
| Tellurium | 4.456 | 5.921 | 101.816 | -1.99950 | 0.786973 | 1.05·1015 |
| Short a,b | 0.913 | 5.921 | 4.274 | -1.97716 | 0.000013 | 2.94·1012 |
| Short c | 4.456 | 1.184 | 20.360 | -2.00775 | 0.302008 | 6.17·1011 |
| Long a,b | 17.287 | 5.921 | 1532.374 | -1.97145 | 1.46827 | 8.20·109 |
| Long c | 4.456 | 30.307 | 521.151 | -1.98165 | 1.38036 | 2.41·1010 |
Te unit cell fractional coordinates are -0.2636, 0.0 ,1/3. The symmetry operations of space group P3121 then populate the unit cell with three atoms total (six half-atoms in the native structure). All 27 permutations of an arbitrary 0.389 change were evaluated through all three fractional coordinates added (P), subtracted (M), or unchanged (0). CHI was progressively calculated with 401 samplings from a 9 Å radius ball containing 84-94 atoms to a 10,000 Å radius ball containing 123.4 billion atoms in each test case.
Table XVI. Te DISTORTED FRACTIONAL COORDINATES
| Fractional Coordinate | Change | Value | Mark |
|---|---|---|---|
| a/x | none +0.389 -0.389 |
-0.2626 +0.1254 -0.6526 |
0 P M |
| b/y | none +0.389 -0.389 |
0.0 +0.3890 -0.3890 |
0 P M |
| c/z | none +0.389 -0.389 |
1/3 +0.722333... -0.055666... |
0 P M |
Table XVII. Te DISTORTED FRACTIONAL COORDINATES DATA
| Change, a/x,b/y,c/z | Slope | Intercept | Change, a/x,b/y,c/z | Slope | Intercept | |
|---|---|---|---|---|---|---|
| P 0 0 | -2.01944 | 0.901199 | M 0 0 | -2.02110 | 0.811078 | |
| 0 P 0 | -1.99126 | 0.720836 | 0 M 0 | -1.99929 | 0.779414 | |
| 0 0 P | -1.99906 | 0.798343 | 0 0 M | -1.99987 | 0.798708 | |
| P P 0 | -1.99798 | 0.775438 | M M 0 | -1.99103 | 0.718670 | |
| P 0 P | -1.99552 | 0.864120 | M 0 M | -2.02444 | 0.848134 | |
| 0 P P | -1.99069 | 0.691879 | 0 M M | -1.99191 | 0.750860 | |
| P M 0 | -1.99173 | 0.759762 | M P 0 | -2.00055 | 0.783633 | |
| P 0 M | -1.99590 | 0.865412 | M 0 P | -2.02192 | 0.844351 | |
| 0 P M | -1.99736 | 0.705094 | 0 M P | -2.00640 | 0.783672 | |
| P P M | -2.00477 | 0.779102 | M M P | -1.99885 | 0.708784 | |
| P M P | -2.00139 | 0.764053 | M P M | -2.00811 | 0.795166 | |
| M P P | -2.00692 | 0.805269 | P M M | -1.99445 | 0.741966 | |
| P P P | -1.99071 | 0.744485 | M M M | -1.99097 | 0.692458 | |
| 0 0 0 Tellurium |
-1.99950 | 0.786973 |
Theory predicts an exact -2 slope. The less positive the intercept the more parity divergent is the lattice. Unit cell volume - smaller volume is more divergent - is much more important than atom placement within the unit cell of an acceptable parity pair space group.
Dr. Penelope Smith at Lehigh University notes that CHI is a connection between eigenvalues, special functions, and their representation theory with solid angles and exponentials of fractions of pi. The intercept is now the solid angle subtended by the smallest vertex angle of a polyhedron (the supplement of its dihedral angle) defined by the c-axis helix,
log(1-CHI)= -2[log(radius)] + [(180-) (
)/60] -
(is the smallest vertex angle in the helix. The slightly distorted tetrahedral O-Si-O helix angle is 110.56° vs. 109.47° undistorted)
log(1-CHI) = -2[log(radius)] + 0.494277
3-cm quartz test mass has CHI = 1 - 1.387·10-16, theory
3-cm quartz test mass has CHI = 1 - 1.535·10-16, graph fit
Subtended solid angle was tested against explicit calculation for quartz, tellurium, distorted tellurium unit cells, and berlinite aluminum phosphate (double length c-axis) that all express rigorous QCM DSI=0 COR=1 regardless of atom labeling or connectivity. It works to 10% difference/average values. As the standard deviation of calculated log(1-CHI) is typically 0.997 units, the two routes to fitting CHI give indistinguishable values.
The optimum crystal structure would have the
The parity Eötvös experiment using parity pair single crystal tellurium, cinnabar, or quartz is astounding robust against a real world minor fraction of crystal structural imperfections and impurities. No heavy atom crystal lattice is substantively better than single crystal tellurium, cinnabar, or quartz for achieving maximum parity divergence as Eötvös experiment test masses.
| Hexagonal Cylinder | Lattice CHI | Total Atoms |
Unit Cells | Volume, Å3 |
Inertial Disparity* |
|---|---|---|---|---|---|
| Tellurium unit cell positions 7 helices x 5 atoms 19 helices x 9 atoms 37 helices x 13 atoms 61 helices x 16 atoms 91 helices x 20 atoms 127 helices x 23 atoms 169 helices x 27 atoms 217 helices x 30 atoms 271 helices x 34 atoms |
0.018926 0.672986 0.949332 0.971947 0.988757 0.987677 0.986497 0.992871 0.983477 0.997870 |
6 35 171 481 976 1820 2921 4563 6510 9214 |
1 12 57 160 325 607 974 1521 2170 3071 |
102 1,189 5,811 16,344 33,164 61,844 99,256 155,051 220,940 312,711 |
64.00 % 13.55 % 5.337% 4.132% 0.920% 0.930% 0.547% 0.796% 1.181% 0.226% |
Selenium and tellurium are exceptional for small unit cell 100% heavy atom content forming identical helices. Next-nearest neighbor distances are almost identical (3.436 Å and 3.491 Å respectively), but selenium bonds are shorter (2.373 Å and 2.835 Å). Selenium's fragile lattice is disordered by physical manipulation, and the grey allotrope cannot be obtained as sufficiently large single crystals by solution growth. Tellurium and selenium display identical variation of CHI with spherical radius despite selenium having a 17.2% shorter pitch when scaled to the same helical radius. The mercury sublattice of cinnabar duplicates the tellurium lattice. It does not confer "tellurium breath" nor does it react with gold during vacuum gilding.
Large tellurium crystals obtain by Czochralski growth and annealing under
hydrogen (50-200 hours at 320-380° C)[110]
which further removes oxygen, sulfur, selenium, arsenic, lead... as
volatile hydrides. Physical helicity has the same sense as optical
rotation (±55.6°/mm at 5000 nm[95]).
Crystals have easy cleavage planes along
.
Typical dislocation densities are 1-3·104/cm3
with a hole concentration of 1014/cm3 (intrinsic
p-type semiconductor). A single crystal tellurium right cylinder two
centimeters in diameter and long contains 1.83·1015
helices for a summed axial length of 3.66·1013 meters
(33.9 light-hours; 3.1 times the solar system's diameter). Each helix
has 3.38·107 360° turns. Both elements' helices
are remarkably isolated in space (view with
CHIME plug-in;
hold left mouse click and drag; right mouse click for menu;
reduced window eases stereoimage fusion).
A classical Eötvös experiment opposes test masses' nuclear binding energies/baryon. Riley Newman's 2.2°K Eötvös balance[48] will oppose Be and Mg (weighted for natural isotopic abundance[111]). Neutron (939.565330 MeV) and proton (938.271998 MeV) average mass equivalent, weighted for 16 protons and 17.3202 neutrons (magnesium isotopic abundance), is 938.944286 MeV.
Be = 6.462844 MeV/baryonA one centimeter diameter
Mg = 8.265129 MeV/baryon
[Mg - Be]/[(17.3202n+16p)/33.3202] = 0.1919%
Cultured quartz is sold as
multi-kilogram single crystals of both chiralities. The
-quartz
lattice (view with CHIME
plug-in)
contains conflicting helices: 6-fold helices with long axes
parallel to the z-axis are of opposite chirality to parallel
12-fold helices; 4-fold helices with the 12-fold helices'
chirality form a 60° grid weaving through the xy
plane. Care must be taken not to heat quartz near 573° C
during working to avoid a first order twinning transition.
Quartz is a potentially poorer geometric test mass than tellurium
for its conflicting helices and lower average atomic weight.
However, quartz is hydrothermally grown to 20 kg single crystals
whereas tellurium is a monumental struggle for Czochralski growth
to one centimeter single crystals.
Quartz crystal imperfections at all scales degrade its resonant acoustic quality factor Q,
Q = 2Infrared OH-stretch absorption at 3410, 3500 or 3585 cm-1 is used to predict Q at 5 MHz[112], EIA Standard 477-1, JIS C 6704, and IEC 60758, e.g.,(energy stored)/(energy lost) each cycle.
Alpha = (A3500 - A3800)/Ywhere A is absorbance at the given wavenumber and Y is the pathlength in centimeters of a Y-cut crystal (z-region material, as opposed to +x, -x, or s). Proton impurities in quartz terminate otherwise continuous ~Si-O~ helices as helix~O-H. Proton uptake varies as crystal growth rate. Slower growth gives higher Q.
| Grade | Minimum Q at 5 MHz | Alpha | A3410 | A3500 | A3585 |
|---|---|---|---|---|---|
| Aa | 3.8·106 | 0.015 | 0.075 | 0.026 | 0.015 |
| A | 3.0·106 | 0.024-0.033 | 0.082 | 0.033 | 0.024 |
| B | 2.4-2.2·106 | 0.045-0.050 | 0.100 | 0.045 | 0.050 |
| C | 1.8·106 | 0.060-0.069 | 0.124 | 0.060 | 0.069 |
| D | 1.4-1.0·106 | 0.100-0.120 | 0.145 | 0.080 | 0.100 |
| E | 1.0-0.5·105 | 0.160-0.250 | 0.190 | 0.120 | 0.160 |
The properties of a potential field depend only on position. The amount of energy gained or lost is independent of what path is taken start to finish. The integral of potential over path to give energy only depends upon the end points. Green's function is an integral kernel that can solve an inhomogeneous differential equation with boundary conditions. Green's function only depends on the distance between the source and the measured field points.
http://www.maths.soton.ac.uk/staff/Andersson/MA361/node46.html The gravitational potentials of configurations (triaxial ellipsoids, spheroids, spheres, disks) in Newtonian gravity, i.e. the potentials derived by integration of the Poisson equation Green's function 1/|r - r'| over the volume of the configuration, are well known. A Green's function solution is unique.
Consider a parity pair of
-quartz
test masses in the weak field limit (Newtonian). Choose a z-axis
position such that a silicon is centered at the same unit cell
position in both space groups P3121 and P3221.
Spatial distribution of the four oxygens around that silicon then
define lattice chirality. Said oxygens are in positions "R" in the
R-enantiomorph and "S" in the S-enantiomorph. Green's
function G(x,y) has two arguments,
x = position of source
y = position of field potential measurement
Suppose G(x,y) varies in x on an angstrom scale. A function maximum falls on the central silicon. The next function maxima are at position "R" but miss position "S." There would then be a different answer for R- versus S-enantiomorphs. Can this obtain, and on what scale? Laplace's equation describing the behavior of gravitational potential is symmetric to parity inversion,
Replacing (x,y,z) by (-x,-y,-z) does not change anything. The only component of gravitation is the radial one, and it only sees overall density (identical for enantiomorphic crystals). A gravitational parity anomaly must have non-Newtonian origins.
From general topological arguments,
G(x,y) = K[dist(x,y)](2-N)where "K" is a scaling constant, "N" is the dimension of space (3 not 4 for traditional Relativity), and "dist(x,y)" is the distance between x,y (ignoring details about timelike components, retarded potentials, etc.). Where would subatomic-scale wiggles arise to allow a gravitational parity anomaly? Self-gravitation would require the nuclear masses to be enormous to give a macroscopic effect. The average nearest neighbor internuclear Si-O distance in quartz is 1.609 Å. Such small wavelength, high frequency components have no basis for origin. (A 0.161 nm photon has energy ~7.7 keV compared to Si-O bond strength of 8.3 eV.)
What are the fluctuation symmetry and radius scale of CHI as radius increases? The symmetry is explicit. A radial increment sufficient to add atoms to the existing solid sphere of lattice will always do it in mirror image along all coordinate axes, space group P3121 versus P3221.
The minimum radius increment that will add atoms to the existing solid sphere of lattice decreases as radius increases. It is remarkably small even at small radii. Green's function requirements for a gravitational parity anomaly - incommensurate structure and a characteristic scale much smaller than atomic lattice spacings - are fulfilled. 1 fm = 0.00001 Å.
| Radius Interval, Å | Radius Increment, fm |
Plot |
|---|---|---|
| 100 - 101.50000 200 - 201.50000 |
100.0 100.0 |
Graph 1 |
| 100 - 100.45000 300 - 300.04500 |
100.0 10.0 |
Graph 2 |
| 900 - 900.00450 2700-2700.00045 |
1.0 0.1 |
Graph3 |
Graph 1 shows a visibly different frequency of CHI fluctuations for 100 Å and 200 Å starting radii given the same radius increments. Graph 2 and Graph3 show that multiplying the starting radius by three and dividing the radius increment by ten gives an apparently constant CHI fluctuation frequency. Multiplying the radius by 3.16228 is stable over a broad observed range. If RÅ is the starting radius in angstroms and rfm is the corresponding radius increment in femtometers that always adds atoms, then
rfm = 106/(RÅ)2A 0.5 cm radius test mass always adds atoms, has CHI fluctuations, with a radius increment of 4·10-10 fm. Oxygen and silicon nuclear diameters are 6.05 and 7.29 femtometers respectively. Thermal fluctuations are ~5% of bond length.
Chirality is not a point phenomenon. It is demonstrated that enantiomorphic centimeter-diameter quartz balls are deeply asymptotic to theoretical maximum parity divergence. As the diameter decreases the parity divergence decreases. Chirality and parity divergence abruptly vanish at scales smaller than a body-centered SiO4 tetrahedron, or a radius of 01.609 Å.
| Contents | Atoms | CHI | DSI | COR |
|---|---|---|---|---|
| SiO4 | 5 | 0.000238 | 0.658392 | 2 |
| SiO4Si4 | 9 | 0.606391 | 0 | 1 |
| unit cell | 11 | 0.408110 | 0 | 1 |
Green's function monotonically increases with the number of massed points included in a spherical envelope of increasing diameter. Parity divergence oscillates about its trend line with significant amplitude. Green's function analyses do not constrain parts-per-trillion gravitation parity anomalies.
R = [R = compactified dimension radiusc]/(Msc2)](Mp/Ms)(2/n)
The "extra" six dimensions loosely comprise one charge dimension, two isospin
dimensions, and three color dimensions. Their physical meaning is debatable.
Below compactified dimensions' radius gravity non-classically varies as
1/r(2+n). At larger spans the anomaly exponentially decays as
a Yukawa potential, [1 +
e-R/
].
If compactified dimensions exist, spacetime can be homogeneous but not
isotropic at small scales. The parity Eötvös experiment is a
powerful test of spacetime isotropy at small scales.
| Compactified Dimensions | Anomaly Radius, Å |
Empirical Observation, Lower Limit |
|---|---|---|
| One | 1021-1023 | planetary orbits affected; wrong |
| Two | 106-107 | 1/r2 deviates; not at 0.01 mm[113] |
| Three | 10 | crystal unit cells; (parity Eötvös) |
| Four | 10-1-3·10-2 | 200x uranium nuclear diameter; 1/18 Bohr hydrogen diameter |
| Five | 10-2-10-3 | 7x uranium nuclear diameter |
| Six | 10-4 | 2/3 uranium nuclear diameter |
| Seven | 2·10-5 | proton Compton wavelength |
Gravitation empirically varies as 1/r2 in 59 - 1150 Å effective gap separations (9600 - 10,690 Å center of mass separation) in atomic force microscope Casimir Effect experiments[116]. An active radius (with decay at its edges) implies a characteristic anomalous volume[117] whose contents' geometry interacts with its n-space container. Parity pair Eötvös experiments directly probe three to four compactified dimensions.
The emergent scale of
-quartz
parity is ~0.484 nm. Given a gravitational parity interaction at much
smaller scale, would it show? Consider a deep bed of close-packed
bowling balls and a deep bed of monodisperse 1-micron radius silica
balls. They have identical void space, 25.952 vol-%
(1-[
/3
2])
and identically shaped voids. A methane molecule has an effective
diameter of 0.000409 microns [118].
Methane roars through the bowling balls but exceedingly slowly
diffuses through the silica balls.
For cubic or hexagonally close-packed identical balls with radius 1,
tetrahedral holes will contain a ball with radius [(
6)/2]-1 or 0.2247.
Thus 1-micron radius silica spheres have voids holding 0.4495 micron
diameter spheres. This is 1100X larger than methane's effective diameter.
The four trigonal windows to each tetrahedral hole will contain a sphere
with radius 0.1547 radius or 0.3094 micron diameter in our case. Methane
can arithmetically freely pass through the silica ball bed by a generous
factor of 756, though in the real world it certainly doesn't - not by a
long shot. A gravitational non-interaction cannot be arithmetically
discounted by "common sense."
For three mutually tangent spheres with radii r1 r2 r3 there is the Soddy circle solution:
r4 = (r1r2r3)/{r1r2 + r1r3 + r2r3 (±)2The positive solution is the inscribed fourth circle tangent to all three. (The negative solution is the circumscribed fourth circle tangent to all three.) Octahedral and cubic lattice holes are larger in radius and have larger radiused windows.[r1r2r3(r1 + r2 + r3)]}
If gravitation did have an antisymmetric interaction with maximal parity-pair divergent crystal lattices, a very small scale for gravitational granularity might have difficulty "oozing through," though the spacetime interpretation (with Heisenberg uncertainty?) is certainly more recondite than 3-D diffusion.
Carbon, nitrogen, and oxygen atoms have similar small masses, and hydrogen is negligible. Light atoms have perceptible de Broglie wavelengths and participate in tunneling reactions[120]. Nucleic acids, proteins, sugars... CHNO organics in general are uninteresting for being much more like flat vacuum than tellurium:
| Substance | Mean atomic weight |
Formula (space group) | Comments |
|---|---|---|---|
| tellurium | 127.60 | Te (P31,221) | 99.98% chiral rest mass |
| PdSbTe | 118.59 | PdSbTe (P213) | 99.98% chiral rest mass |
| 116.33 | HgS (P31,221) | 99.97% chiral rest mass | |
| 20.03 | SiO2 (P31,221) | 99.97% chiral rest mass | |
| benzil | 8.09 | C14H10O2 (P31,221) | 99.97% chiral rest mass |
| tartaric acid | 9.38 | C4H6O6 | 2 chiral centers |
| cyclooctaamylose | 7.72 | C48H80O40 | 40 chiral centers |
| palytoxin | 6.55 | C129H223N3O54 | 64 chiral centers |
| insulin | 7.37 | C257H383N65O77S6 | 51 amino acids |
| somatotropin | 7.16 | C990H1529N263O299S7 | 191 amino acids |
Chiral polymers[121] have loosely packed
crystal lattices. Aggregated helicenes[122] can have
[
]D=170,000°
(1400°/mm gyrotropy neat) as can neat cholesteric (nematic-C)
liquid crystals, but optical chirality is irrelevant.
Binaphthyls are [5]helicenes less a ring junction. Jacobsen's ligand
chelates uranyl[123], tin, or
lead[124] with small geometric chiralities.
Helicates[125] including
iron[126] and silver
helicates[127] ((R,R)-ligand
gives (S)-helices) have large unit cell volumes. An alternating
platinum-silver P61 helix[128]
has a 7898.1 Å3 unit cell. A claimed intensely chiral
octahedral complex[129],
tris[1,2-dithiolatophenylenetungsten(IV)][130],
has a 5649.0 Å3 unit cell.
Equivalence Principle violation falsifies metric theories of gravitation (leaving affine, teleparallel, and noncommutative theories unscathed). Contrasted test mass compositions afforded 400+ years of null results; calculated parity pair test masses have never been examined. A non-null parity Eötvös experiment supercedes parity-violating energy difference[131] explanations of biological homochirality.
Gravitation applies to free elementary particles (single neutrons
fall[132]). Classical physics, relativity,
and quantum mechanics are all point phenomena. A "point" spans the
Planck length[133],
(
G/c3)1/2
or 1.616·10-26 nm and thus implies a spherical
volume approximating 2.21·10-78 nm3.
Three atoms define an achiral plane. Geometric parity is an
emergent phenomenon vanishing at smaller than unit cell scales. A
tellurium unit cell contains three atoms as six half-atoms in the
walls of a 0.1018 nm3 irreducible configuration. A
non-null parity Eötvös experiment breaches "point
phenomenon" by a volu